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Femtosecond laser-induced optical kerr dynamics in CS2/alkane binary solutions

✍ Scribed by Constantinos Kalpouzos; Dale McMorrow; William T. Lotshaw; Geraldine A. Kenney-Wallace


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
841 KB
Volume
150
Category
Article
ISSN
0009-2614

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✦ Synopsis


The molecular dynamics of CS2 are investigated in binary liquid solutions with alkane solvents of varying viscosity. The nondiffusive, subpicosecond nuclear responses reveal the influence of many-body effects as they are manifested in the changing local intermolecular potentials on dilution and the role of dynamical fluctuations of these potentials that occur on a time scale of r 425 fs.