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Femtosecond Infrared Study of the Dynamics of Solvation and Solvent Caging

โœ Scribed by Yang, Haw; Snee, Preston T.; Kotz, Kenneth T.; Payne, Christine K.; Harris, Charles B.

Book ID
126398149
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
105 KB
Volume
123
Category
Article
ISSN
0002-7863

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Studies are reported of the dynamics of proton-transfer reactions, with sub-picosecond time resolution, in solvent cages. The acid-base system studied in a molecular beam is I-naphthol as a solute and ammonia (or water) as a solvent, with the number of solvent molecules (n ) varying. At the threshol