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Femtosecond Dynamics of Transition States and the Concept of Concertedness: Nitrogen Extrusion of Azomethane Reactions

✍ Scribed by Diau, Eric W.-G.; Abou-Zied, Osama K.; Scala, Alfred A.; Zewail, Ahmed H.


Book ID
126873181
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
40 KB
Volume
120
Category
Article
ISSN
0002-7863

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Femtosecond elementary dynamics of trans
✍ Sang Kyu Kim; Ahmed H. Zewail πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 624 KB

In this Letter, we report studies of the femtosecond dynamics of transition states and asymmetric a-cleavage in Norrish type-I reactions. Systematically, we consider the dynamics of dissociation along two reaction coordinates in methyl ethyl ketone and diethyl ketone, and compare these results with