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FeCl3·6H2O and TfOH as Catalysts for Allylic Amination Reaction: A Comparative Study

✍ Scribed by Paz Trillo; Alejandro Baeza; Carmen Nájera

Book ID
112082749
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
663 KB
Volume
2012
Category
Article
ISSN
1434-193X

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📜 SIMILAR VOLUMES

[Rh3O(OAc)6 (H2O)3]OAc as a homogeneous
[Rh3O(OAc)6 (H2O)3]OAc as a homogeneous catalyst for selective enone formation by allylic oxidation of olefins
✍ Sakae Uemur; Suresh R. Patil 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 202 KB

Treatment of several cyclic olefins and allylbenzene with a catalytic amount of [Rh30(OAc)6(H20)3]OAc in acetic acid in the presence of t-butvl hvdroperoxide affords the corresponding a,8-unsaturated carbonyl compounds highly selectively via an ionic pathway.