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Features of styrene polymerization initiated by azo-bis-isobutyronitrile in the presence of Al(C2H5)3

✍ Scribed by Z.M. Dzhabiyeva; P.Ye. Matkovskii; Ye.L. Pechatnikov; N.A. Byrikhina

Book ID
116047577
Publisher
Elsevier Science
Year
1985
Weight
440 KB
Volume
27
Category
Article
ISSN
0032-3950

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Non-ideality in vinyl polymerizationβ€”IV.
Non-ideality in vinyl polymerizationβ€”IV. Kinetics of polymerization of vinyl acetate in benzene initiated by azo-bis isobutyronitrile (AIBN)
✍ Pramil C. Deb; Swati Ray πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 257 KB

Vinyl acetate was polymerized in bulk and in benzene at 50Β°C using a wide range of concentrations of azobisisobutyronitrile. Values offk (the efficiency of initiator) and kr,,/klk p (the characteristic constant of primary radical termination) were found to be 0.53 and 2.00 x 104 respectively from da