𝔖 Bobbio Scriptorium
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Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization of Methyl Methacrylate and Styrene at Ambient Temperature

✍ Scribed by Lili Zhou; Zhengbiao Zhang; Zhenping Cheng; Nianchen Zhou; Jian Zhu; Wei Zhang; Xiulin Zhu


Book ID
112141327
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
229 KB
Volume
213
Category
Article
ISSN
1022-1352

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Fe(0) Powder/CuBr2-Mediated “Living”/Con
✍ Lili Zhou; Zhengbiao Zhang; Zhenping Cheng; Nianchen Zhou; Jian Zhu; Wei Zhang; 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 731 KB

## Abstract The combination of zero‐valent iron (Fe(0) powder) and copper(II) bromide was used to mediate the polymerization of methyl methacrylate (MMA) or styrene (St) at 25 ° C. The results demonstrated that the solvent played an important role on the polymerization rate and molecular‐weight con

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## Abstract Organostibine‐mediated controlled/living radical polymerization of MMA was successfully achieved in room temperature ionic liquids (RTILs) [bmim]Tf~2~N and [bmim]PF~6~. The ln([M]~0~/[M]) increased linearly with increasing reaction time. The number‐average molecular weights of PMMA incr