Fatty acids : VI. The thin-layer chromatographic behaviour of mercury adducts of acetylenic esters and a study of the demercurated products
β Scribed by C.H. Lam; M.S.F. Lie Ken Jie
- Book ID
- 108335122
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 451 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1873-3778
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π SIMILAR VOLUMES
The chromatographic properties of the cis and trans methyl octadecenoates and of some C12 and Cls acetylenic esters on thin layers of silica impregnated with silver nitrate and on some GLC systems are reported. The possibility of identification and separation of these isomers is discussed.
The methoxymercuration-demercuration reactions of all the methyl cis-undecenoates are reported. Oxymercuration reaction of acetylenic esters gives keto-and hydroxy-esters when demercurated with hydrochloric acid and sodium borohydride respectively. Similar reactions are carried out with methyl octad