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Fate of the Intermediate Diradicals in the Caldera: Stereochemistry of Thermal Stereomutations, (2 + 2) Cycloreversions, and (2 + 4) Ring-Enlargements of cis - and trans - 1-Cyano-2-( E and Z )-propenyl- cis -3,4-dideuteriocyclobutanes

✍ Scribed by Doering, W. von E.; Cheng, Xueheng; Lee, Kyuwang; Lin, Zisen


Book ID
120225397
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
329 KB
Volume
124
Category
Article
ISSN
0002-7863

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A complete one-and two-dimensional nuclear magnetic resonance (NMR) study was carried out on the styrene-acrylonitrile (SAN) dimer fraction of a sample of SAN thermal copolymer. A crude sample of SAN oligomers was first fractionated by distillation and then the dimers were isolated by thin-layer chr