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Fast Reductive Ligation of S-Nitrosothiols

✍ Scribed by Hua Wang; Ming Xian


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
321 KB
Volume
120
Category
Article
ISSN
0044-8249

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Under anaerobic conditions S-nitrosothiols 1 a Β± e undergo thermal decomposition by homolytic cleavage of the SΓ€N bond; the reaction leads to nitric oxide and sulfanyl radicals formed in a reversible manner. The rate constants, k 1 , have been determined at different temperatures from kinetic measur