Fast Palladium Catalyzed Arylation of Alkenes Using Bulky Monodentate Phosphorus Ligands

✍ Scribed by Gino P. F. van Strijdonck; Maarten D. K. Boele; Paul C. J. Kamer; Johannes G. de Vries; Piet W. N. M. van Leeuwen

• Book ID: 101280730
• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: English
• Weight: 203 KB
• Volume: 1999
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199907)1999:7<1073::aid-ejic1073>3.0.co;2-t

✦ Synopsis

Complex 1b shows an unprecedented high activity in the the oxidative addition but the alkene coordination/migratory insertion is the rate determining step. Heck reaction. Kinetic studies show that in this system not