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Fast-Ion-Beam Laser Spectroscopy of the B2Σ+-X2Σ+ and B2Σ+-A2Π Systems of SiO+: Deperturbation Analysis

✍ Scribed by R. Cameron; T.J. Scholl; L. Zhang; R.A. Holt; S.D. Rosner

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
430 KB
Volume
169
Category
Article
ISSN
0022-2852

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✦ Synopsis

We have completed a deperturbation analysis of a set of measurements in (\mathrm{SiO}^{+})including seven bands of the (B^{2} \Sigma^{+}-X^{2} \Sigma^{+})system, the ((2,0) \Omega=\frac{1}{2}) sub-band of the (B^{2} \Sigma^{+}-A^{2} \Pi) system, and fine structure intervals of the (v=0) level of the (X^{2} \Sigma^{+})state. The pattern of perturbations in the (B-X) system shows that the assignments of vibrational levels in the (A^{2} \Pi) state made in earlier photoelectron spectroscopy work are incorrect. Deperturbed molecular constants for the three electronic states have been derived. (c) 1995 Academic Press. Inc.

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