Fast atom bombardment mass spectrometry of cyclic hydrido dithio- and dioxycarbene complexes of platinum(II)
β Scribed by R. Bertani; M. Mozzon; R. A. Michelin; R. Seraglia; P. Traidi
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 483 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1076-5174
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β¦ Synopsis
Fast atom bombardment (FAB) m a s spectrometry of the two hydrido carbene compounds trms-I (PPh,),HPt(carbene)] BF, (carbene = &CH,CH,S and COCH,CH,O was studied. Some retrosynthetic processes are involved in the fragmentation pathways. The reactions with NaCl were also studied under FAB conditions and the results were compared with those obtained in solution.
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The fast atom bombardment mass spectra of a series of neutral methanide and ionic carbene platinum(I1) complexes of formula dPePtL, and [dPePt(LH),](BF,), (dPe = (C,H,),PCH,CH,P(C,H,),; L = -C(OCH,)=NCH, , -C(OCH,)=NC,H, , -C(OCH,)=NC,H,p-CH,), respectively are reported. Glycerol, 3-mercapto-1,2prop
Fast atom bombardment (FAB) mass spectrometry has been used to examine a series of rhodium, iridium and platinum orgmometaUic complexes, in wbich a cumdene ligand is attached to the metal in either uor bonding fashion. The most intense ion formed in the rhodium and platinum series is the metal-bis(t
## Abstract A series of 27 Mn(III)βtetraarylporphyrins bearing heterogeneous substituents on the phenyl rings at the meso positions were subjected to positive ion fast atom bombardment mass spectrometry The source spectra yielded the molecular ion and a few peaks confirmative of the chemical struct