Positive-ion fast atom bombardment mass spectra and linked-scan tandem mass spectra were measured for aromatic iodonium salts. The mass spectra usually contain the intact cation of the iodonium salt as the base peak, fragment ions of lower abundance resulting from simple cleavages or rearrangements,
Fast atom bombardment mass spectra of telluronium salts
โ Scribed by Gui-Xiang Fu; Zhang-Lin Zhou; Lu Yu; Yao-Zeng Huang
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 299 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1076-5174
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โฆ Synopsis
Tbe fast atom bombardment (FAB) mass spectra of telluronium salts were studied. The spectra exhibit the intact cation (C') a d cllster ions (I M + C I '). Tbe principal fragment ions in tbe FAB mass spectra of telluronium salts are IRTel', IR,Tel*', IR,Te -HI', IRTeRI", a d [RTeR'+ HI+. Wben tbe anion was IBPh,I-, interesting cluster ioas such as [ M + C -BPh, I + appeared.
๐ SIMILAR VOLUMES
The positive-ion fast atom bombardment (FAB) mass spectra of stibonium salts have been studied. The spectra exhibit an abundant intact cation ( C ' ) and fragment ions resulting from the loss of R, R' or stable neutral species from the cation. The principal fragment ions in the FAB mass spectra of s