(1-13C)Glycerol, D-(1-13C)arabinitol, D-(1-13C)ribitol, D-(1-13C)xylitol, D-(1-13C)glucitol, D-(1-13C)mannitol, and D-(1-13C)talitol have been prepared by NaBH4 reduction of the corresponding (1-13C)aldoses. A comparison of the 1H- (300 and 620 MHz) and 13C (75 MHz) n.m.r. spectra of natural and (1-
✦ LIBER ✦
Far i.r. spectra of symmetric aliphatic ketones C13C27
✍ Scribed by C.H. Burton
- Book ID
- 113374359
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 738 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1386-1425
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## Abstract D.n.m.r. studies have been performed involving the measurement of rates of __trans__‐__cis__ isomerization of aliphatic enamino ketones of the type RCOCHCHNHR~1~, by means of equilibration experiments and the method of finding the coalescence temperature. Simultaneous observation of