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Far-Infrared Spectrum, ab Initio Calculations, Conformational Energy Differences, Barriers to Internal Rotation, and r 0 Structure of Propanal †

✍ Scribed by Durig, J. R.; Guirgis, Gamil A.; Bell, Stephen; Brewer, W. E.


Book ID
121709731
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
240 KB
Volume
101
Category
Article
ISSN
1089-5639

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Microwave spectrum, r0 structure, barrie
✍ James R. Durig; Chao Zheng; Gamil A. Guirgis; Hossein Nanaie 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 164 KB

The microwave spectra of four isotopomers, CH 3 CH 2 12 CHF 2 , CH 3 CH 2 13 CHF 2 , CD 3 CH 2 12 CHF 2 and CD 3 CD 2 12 CHF 2 , of gauche-1,1difluoropropane, in the ground vibrational state were recorded and assigned. From the measured frequencies for the R and Q branches of the a-, b-and c-type tr