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Far-Infrared Rotational Spectra of ZnH and ZnD in theX2Σ+(v= 0) State

✍ Scribed by F.Akif Tezcan; Thomas D. Varberg; Fred Stroh; Kenneth M. Evenson

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
252 KB
Volume
185
Category
Article
ISSN
0022-2852

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✦ Synopsis

Several rotational transitions of zinc hydride and deuteride within the £ Å 0 level of the X 2 S / state have been measured in both electron spin components over the ranges NЉ Å 2 to 10 for ZnH and NЉ Å 9 to 21 for ZnD. A leastsquares fit to these data in combination with low-N microwave data measured by other workers has resulted in improved values of the rotational, fine, and hyperfine structure constants. The values of the proton hyperfine constants are discussed in the context of a molecular orbital analysis of zinc hydride.

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