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Far-infrared and X-ray investigations of the mixed platinum dichalcogenides PtS2−xSex, PtSe2−xTex, and PtS2−xTex

✍ Scribed by G. Kliche


Book ID
103245859
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
398 KB
Volume
56
Category
Article
ISSN
0022-4596

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The reactions of tetrakis(triphenylphosp
✍ Pawan K. Khanna; Christopher P. Morley; Michael B. Hursthouse; K. M. Abdul Malik 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 431 KB

Treatment of tetrakis(tripheny1phosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a I : I mixture of [PtCl,(PPh,)J and the new compound [Pt(Se,CH,) (PPh,)J, which