Far-infrared absorption in liquid water
β Scribed by J.B. Hasted; S.K. Husain; F.A.M. Frescura; J.R. Birch
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 297 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The results of new measuremems of the far-infrared optical constant OF hquld waler out 10 4 cm-' a~ 293 K are presented. The+= together with previously published submillimetre wavelength measuremen&. are analysed to show that it is possible to lip the continuous far-infrared-tcrmicrowave absorption spectrum LO classical polar-molecule relaxation theory with added conlribuuons rrom Gaussian oscillator close to 200 and 50 cm-'_ Bolh of these oscillators ha\e been observed in Raman sludles. The 100 cm-' band is well characLerised in infrared measuremenls. but the presenL work represents the first unambiguous identirlcalion of the 50 cm-' band in mrrared observations.
π SIMILAR VOLUMES
The far IIt spectra (6: I.00 cm-l) of gaseous N2C from 34 to 64 bars are reported. The absorpttoa due to the (small) permanent dipole is +cdmpahied by contributions due to dipole-and quadrupoleinduced momenta, the latter being the larger. An acceptable value,' Q(N20) x 8 x 10-26 esu is estimated fro