The synthesis and structural characterisation of a series of cobalt and nickel cages are reported. Eight of these structures contain a [M10(mu3-OH)6(eta2, mu3-xhp),(eta2, mu2-O2CR)6]2+ core (where M = Co or Ni; xhp = 6-chloro- or 6-methyl-2-pyridonate: R = Me, Ph, CHMe2, CH2Cl, CHPh2 or CMe3), where
Families of Polynuclear Manganese, Cobalt, Nickel and Copper Complexes Stabilized by Various Forms of Di-2-pyridyl Ketone
β Scribed by Giannis S. Papaefstathiou; Spyros P. Perlepes
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4βisobutylβ3,5βdi(2βpyridyl)β4__H__β1,2,4βtriazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~
## Abstract As a probe of the dinucleating ability of the known but little studied bisβbidentate ligand 3,5βdi(2βpyridyl)β4β(1__H__βpyrrolβ1βyl)β4__H__β1,2,4βtriazole (pldpt) its reactivity towards MX~2~Β·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^β^ and BF~4~^β^) as well as Cu(ClO~4~)~2~Β·6H~