✦ LIBER ✦

Failure of crystal field theory: an example

✍ Scribed by W. Urland; S.R. Niketić

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 249 KB
Volume: 129
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80406-7

No coin nor oath required. For personal study only.

✦ Synopsis

Crystal field theory fails if one tries to explain the difference in spectra of two tris(aminoacidato)cobalt(III) complexes with practically identical coordination geometry. The application of the angular overlap model with the assumption of anisotropic Co-O interaction gives an explanation for the difference.

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