Carboxyl-terminated poly(2-ethylhexyl acrylate) (CTPEHA) liquid rubbers of different molecular weights and functionalities (LR-1 to LR-6) were synthesized by bulk and solution polymerization techniques. The liquid rubbers were characterized by nonaqueous titration, vapor pressure osmometry, and gel
Failure analysis of rubber toughened epoxy resin
โ Scribed by Vineeta Nigam; D. K. Setua; G. N. Mathur
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 477 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
Abstract
Failure of the blends of epoxy cresol novolac resin (ECN) with varied proportions of carboxy terminated polybutadiene (CTPB) liquid functional rubber was studied. Addition of CTPB improves toughness as reflected in the improvement of tensile, flexural, and impact properties. However, 10 wt % of CTPB was the optimum concentration beyond which a rapid fall of properties, in all cases, was observed. Surface topography of the fractured surfaces, studied by scanning electron microscopy and atomic force microscopy, revealed marked changes in the phase morphology due to addition of rubber and also accounted for the variation of the strength properties. ยฉ 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 861โ868, 2003
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