Factors which control exciplex formation in the 1,3-photoaddition reaction of anisole with olefins

✍ Scribed by R. Srinivasan; J.A. Ors

• Book ID: 103015934
• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 242 KB
• Volume: 42
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(76)80663-x

✦ Synopsis

Quantitative data on the photochemical 1,3-addition of auisolc to a number of olefins Over a range of ccncentrations of the latter are reported. T&e reaction which is believed to proceed via an exciplex intermediate is shown to be influenced by stcric considerations and, perhaps, by the ionization potential of the olefin. No. F44620-72-C-0024 under which this work was Chem. Sot. 90 (1968) 1116;

carried out.