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Factors that affect the formation of metal-carbon bonds in metalorganic mixtures

โœ Scribed by A. G. Ermilov; N. N. Rakova; A. F. Borun; A. M. Dodonov


Book ID
111503775
Publisher
Allerton Press, Inc.
Year
2007
Tongue
English
Weight
162 KB
Volume
48
Category
Article
ISSN
1067-8212

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Nickel acetylacetonate effectively catalyses the carbon-carbon bond formation between malononitrile and P-dicarbonyls. In these metal-catalysed reactions malononitrile behaves as an electrophile towards the intercarbonylic carbon, so exhibiting a reverse reactivity compared with that one under basic