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Factors Controlling the Substrate Specificity of Peroxidases: Kinetics and Thermodynamics of the Reaction of Horseradish Peroxidase Compound I with Phenols and Indole-3-acetic Acids

โœ Scribed by Candeias, Luis P.; Folkes, Lisa K.; Wardman, Peter


Book ID
120496504
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
117 KB
Volume
36
Category
Article
ISSN
0006-2960

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The peroxidase catalyzed degradation of indole-3-acetic acid (IAA) results in the formation of indole-3-methanol (IM) in the presence of phenolic compounds or in 3-hydroxymethyloxindole (HMOx) in their absence. Apparently the phenols compete with a methyleneindolenine intermediate for HzO 2 which is