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Factors Affecting the Selectivity of Formation of Epoxides During the Oxidation of Substituted Styrenes

โœ Scribed by V. Ya. Suprun; I. A. Opeida

Book ID
110291694
Publisher
Springer
Year
2001
Tongue
English
Weight
67 KB
Volume
37
Category
Article
ISSN
0040-5760

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Rearrangement of styrene oxide with (a) LiC104 and (b) BF3 to give phenylethanal exhibits diastereotopic selection with migration of the hydrogen trans to the phenyl group being favoured 1.4 and 1.14 times respectively. The rate of rotation about the Cl -C2 bond of the intermediate is comparable, bu