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Factors Affecting the Electronic Ground State of Low-Spin Iron(III) Porphyrin Complexes

✍ Scribed by Ikeue, Takahisa; Ohgo, Yoshiki; Saitoh, Takashi; Yamaguchi, Tatsuya; Nakamura, Mikio

Book ID
127257675
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
173 KB
Volume
40
Category
Article
ISSN
0020-1669

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Hyperfine Shifts of the 13C-NMR. in low
Hyperfine Shifts of the 13C-NMR. in low spin iron(III) porphyrin complexes
✍ Kurt WΓΌthrich; Rudolf Baumann πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 German βš– 676 KB

## Abstract The ^13^C‐NMR. in Zn(II)(Porphin), Fe(III)(Porphin)(CN~2~), Zn(II)(Tetraphenyl‐porphin), and Fe(III)(Tetraphenylporphin)(CN~2~) have been identified, and the ^13^C hyperfine shifts in the iron complexes evaluated. It was found that dipole‐dipole coupling with the electron spin localized