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Factors Affecting Migration of Tertiary Alkyl Groups in Reactions of Alkylboronic Esters with Bromomethyllithium

โœ Scribed by Elliott, Mark C.; Smith, Keith; Jones, D. Heulyn; Hussain, Ajaz; Saleh, Basil A.


Book ID
118739255
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
572 KB
Volume
78
Category
Article
ISSN
0022-3263

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## Abstract Pyridinium and isoquinolinium ylides (**__7__** and **__12__**) derived from malonic ester react in an unusual manner with isocyanates giving the new pyridinium ylide (**__9__**) and the new isoquinolinium ylide (**__14__**). __C__ โ†’ __N__ Migration of the COOEt group takes place at roo