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Faclie Regeneration of Carbonyl Compounds from 1,3-Dithiane 1-Oxides via 1-Ethoxy-1,3-dithianium Salts

✍ Scribed by Dr. Ingfried Stahl; Jürgen Apel; Dipl.-Chem. Rainer Manske; Prof. Dr. Jürgen Gosselck


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
219 KB
Volume
18
Category
Article
ISSN
0044-8249

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Nitrogen-rich mesoions have been synthesized by the reac-give aminotetrazolium salt 9, deprotonation of which yielded the corresponding conjugate base 3. Hard nucleophiles at-tion of the 5-chloro-1,3-diaryltetrazolium salt 1 with various nitrogen nucleophiles. The reactions with aqueous ammonia tack