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Facile β-Alkoxycarbonylation and β-Acylation of α,β-Unsaturated Lactones and Esters via the Phosphoniosilylation Process.

✍ Scribed by Jung Hyun Kim; Sun Ho Jung


Publisher
John Wiley and Sons
Year
2005
Weight
21 KB
Volume
36
Category
Article
ISSN
0931-7597

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Use of Ph3P=N-Li: Synthesis of α,β-unsat
✍ Henri-Jean Cristau; Amer Hammami; Elaine Torreilles 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 191 KB 👁 1 views

The reaction of Ph 3 P‫ס‬NLi with various ␣,b-unsaturated esters gives access to new N-(␣,b-unsaturated acyl) phosphinimines, which can undergo intramolecular aza-Wittig reactions