Facile synthesis of unsymmetrical benzotetrathiafulvalenes via cleavage of the corresponding hexathioorthooxalates
โ Scribed by Charles M. Lindsay; Keith Smith; Charles Allan Brown; Kathleen Betterton-Cruz
- Book ID
- 104232529
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 236 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Unsymmetrical hexathioorthooxalates
of types ( 1) and ( 2) undergo elimination of dialkyl disulfide on heating in an organic solvent; the reaction, which is catalyzed by acid, proceeds without fission of the central C-C bond and provides the first general, high yield synthesis of unsymmetrical benzotetrathiafulvalenes of types (3_) and ( 4).
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