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Facile synthesis of unsymmetrical benzotetrathiafulvalenes via cleavage of the corresponding hexathioorthooxalates

โœ Scribed by Charles M. Lindsay; Keith Smith; Charles Allan Brown; Kathleen Betterton-Cruz


Book ID
104232529
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
236 KB
Volume
25
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Unsymmetrical hexathioorthooxalates

of types ( 1) and ( 2) undergo elimination of dialkyl disulfide on heating in an organic solvent; the reaction, which is catalyzed by acid, proceeds without fission of the central C-C bond and provides the first general, high yield synthesis of unsymmetrical benzotetrathiafulvalenes of types (3_) and ( 4).


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