FACILE SYNTHESIS OF SOME NEW FLUORINE CONTAINING SPIRO [3H-INDOLE-3,2′TETRAHYDRO-1,3-THIAZINE].2,4′(1H)-DIONES
✍ Scribed by Dandia, Anshu; Sharma, C. S.; Saha, Mitali
- Book ID
- 126585805
- Publisher
- Taylor and Francis Group
- Year
- 1998
- Tongue
- English
- Weight
- 400 KB
- Volume
- 139
- Category
- Article
- ISSN
- 1042-6507
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## Abstract An auto oxidation‐rearrangement product 4 was isolated from a high dilution reaction of ninhydrin with 3,4,5‐trimethoxyaniline in water. A general synthesis of this compound and its derivatives 4–6 was devised by oxidation of tetrahydroindeno[1,2‐__b__]indol‐10‐ones 1–3 with sodium peri
The structure of the title compound, C 32 H 23 BrN 2 O 3 ÁH 2 O, is stabilized by intramolecular CÐHÁ Á ÁO interactions, and the molecular packing is stabilized by intermolecular CÐHÁ Á ÁO and NÐHÁ Á ÁN hydrogen bonds.
1 0 0 0 -Methyl-4 0 0 0 -phenyl-1H-indole-3-spiro-2 0 0 0 -pyrrolidine-3 0 0 0 -spiro-1 0 0 00 0 0 -cyclooctane-2(3H),2 0 0