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Facile Synthesis of Chiral α-Difluoromethyl Amines from N-(tert-Butylsulfinyl)aldimines.

✍ Scribed by Ya Li; Jinbo Hu

Publisher
John Wiley and Sons
Year
2006
Weight
24 KB
Volume
37
Category
Article
ISSN
0931-7597

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Highly Diastereoselective Synthesis of α
Highly Diastereoselective Synthesis of α-Difluoromethyl Amines from N-tert-Butylsulfinyl Ketimines and Difluoromethyl Phenyl Sulfone
✍ Dr. Jun Liu; Prof. Dr. Jinbo Hu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 500 KB

## Abstract The first highly efficient and stereoselective difluoromethylation of structurally diverse __N‐tert__‐butylsulfinyl ketimines has been achieved with an in situ generated PhSO~2~CF~2~^−^ anion, which provides a powerful synthetic method for the preparation of a variety of structurally di