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Facile synthesis of (2E,4E)-dienoic esters via stereoselective isomerization of 2-ynoic esters

✍ Scribed by Dawei Ma; Xiyan Lu

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 103 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80631-6

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✦ Synopsis

2E,

)-Dienoic esters were synthesized stereoselectively from the corresponding 2-ynoic esters in high yield under the catalysis of an iridium hydride or ruthenium hydride complex.

Recently, we reported the highly stereoselective

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