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Facile Synthesis and Palladium-Catalyzed Cross-Coupling Reactions of 2,3-Bis(pinacolatoboryl)-1,3-butadiene

✍ Scribed by Masaki Shimizu; Takuya Kurahashi; Katsuhiro Shimono; Kei Tanaka; Ikuhiro Nagao; Shin-ichi Kiyomoto; Tamejiro Hiyama


Book ID
112005309
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
328 KB
Volume
2
Category
Article
ISSN
1861-4728

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A synthesis of 2-aryl-. 2-(1-alkenyl)-, and 2-alkyl-1,3-butadiene derivatives (2) by the palladiumcatalyzed cross-coupling reaction of 2,3-bumiienyl carbonatea (1) with 9-alkyl-9-bicyclo[3.3.llmman~ (9-alkyl-9-BBN), 1-aknylboronic acids, or arylbcmdc acids is described. The reaction pmeeded regiosek