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Facile syntheses of tetraalkylchlorin and tetraalkylporphyrin complexes and comparison of the structures of the tetramethylchlorin and tetramethylporphyrin complexes of nickel(II)

✍ Scribed by Ulman, Abraham; Gallucci, Judith; Fisher, Diane; Ibers, James A.

Book ID
126172783
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
407 KB
Volume
102
Category
Article
ISSN
0002-7863

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## Abstract The two trinuclear nickel(II) complexes, Ni~3~(C~13~H~15~N~2~O~3~)~2~(C~5~H~5~N)~4~ (1) and Ni~3~(C~13~H~15~N~2~O~3~)~2~(C~5~H~5~N)~2~‐ (C~3~H~7~NO)~2~ (2), were prepared by the reaction of Ni(OAc)~2~Β·4H~2~O with __N__‐hexanoylsalicylhydrazide. The crystal structures of complexes were d