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Facile syntheses of a hexasaccharide and a nonasaccharide related to the cell wall D-mannan of yeast Candida albicans

✍ Scribed by Jun Ning; Fanzuo Kong

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 213 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02625-2

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✦ Synopsis

A highly efficient strategy for the preparation of D-manno-hexa-and nonasaccharides related to the cell wall D-mannan of yeast Canddda albicans having ct-( 1-*6)-and ¢t-( 1--~2)-linkages has been developed using 6-O-acetyl-2-O-benzoyl-3,4-di-O-benzyl~-D-mannopyranosyl trichloroacetinfidate (7) as the key glycosyl donor in the "Inverse Schmidt" procedure.

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