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Facile Reduction of Tungsten Halides with Nonconventional, Mild Reductants. 2. Four Convenient, High-Yield Solid-State Syntheses of the Hexatungsten Dodecachloride Cluster W 6 Cl 12 and Cluster Acid (H 3 O) 2 [W 6 (μ 3 -Cl) 8 Cl 6 ](OH 2 ) x , Including New Cation-Assisted Ternary Routes

✍ Scribed by Kolesnichenko, Vladimir; Messerle, Louis

Book ID
124158324
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
48 KB
Volume
37
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES

Facile Reduction of Early Transition Met
Facile Reduction of Early Transition Metal Halides with Nonconventional, Mild Reductants. Part 5. Gallium and Gallium Dichloride, New Solid-State Reductants in Preparative Transition Metal Chemistry. New, Lower Temperature Syntheses and Convenient Isolation of Hexatantalum Tetradecachloride Octahydrate, Ta6(μ-Cl)12Cl2 (OH2)4×4H2O, and Synthesis and Solid-State Structure of a Tetraalkylammonium Derivative, [N(CH2Ph)Bu3]4 [Ta6(μ-Cl)12Cl6], of the Reduced [Ta6(μ-Cl)12]2+ Cluster Core.
✍ Daniel N. T. Hay; Dale C. Swenson; Louis Messerle 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 2 views