Ξ·1-Vinylidene to Ξ·2-Alkyne Isomerization
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Junes Ipaktschi; Javad Mohsseni-Ala; Sascha Uhlig
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Article
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2003
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John Wiley and Sons
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English
β 175 KB
## Abstract The thermal isomerizations of Ξ·^1^βvinylidene complexes [(Ξ·^5^βC~5~H~5~)(CO)(NO)W=C=CHR] [5a, R = Si(CH~3~)~2~C(CH~3~)~3~; 5c, R = C(CH~3~)~3~] as well as [(Ξ·^5^βC~5~H~5~)(CO)(NO)Mo=C=CHC(CH~3~)~3~] (8), to the corresponding Ξ·^2^β1βalkyne complexes [(Ξ·^5^βC~5~H~5~)(CO)(NO)W(Ξ·^2^βHβCβ‘CβR