Facile exchange of aromatic hydrogen with deuterium in the absence of catalysts. Aromatic diamines
✍ Scribed by Grivas, John C.
- Book ID
- 126906998
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 371 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-3263
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## Abstract A new type of hydrogen‐deuterium exchange reaction in acid media, viz. the exchange of hydrogen atoms of the t‐butyl group, substituted in benzene rings, has been found. The reaction is first‐order in the concentration of the hydrocarbon. There is no simple relation between the rate con
## Abstract Conventional thermal and microwave conditions were compared for hydrogen–deuterium (H/D) exchange reactions of aminobenzoic acids catalysed by NaBD~4~‐activated Pd/C or RhCl~3~ with D~2~O as the deuterium source. We also investigated different NaBD~4~‐activated metal catalysts (includin