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Facile Cycling of Ti-Doped LiAlH 4 for High Performance Hydrogen Storage

✍ Scribed by Liu, Xiangfeng; McGrady, G. Sean; Langmi, Henrietta W.; Jensen, Craig M.

Book ID
120047753
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
152 KB
Volume
131
Category
Article
ISSN
0002-7863

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Reaction stoichiometry between TiCl3 and
Reaction stoichiometry between TiCl3 and NaAlH4 in Ti-doped alanate for hydrogen storage: The fate of the titanium species
✍ Shu Zhang; Cheng Lu; Nobuhiko Takeichi; Tetsu Kiyobayashi; Nobuhiro Kuriyama πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 286 KB

In order to understand the final state of the TiCl 3 dopant during the dehydrogenation and rehydrogenation cycles of NaAlH 4 , we determined the reaction stoichiometry between TiCl 3 and NaAlH 4 by measuring the amount of hydrogen evolution from NaAlH 4 with the varying TiCl 3 -load. We found that: