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Facile conversion of CF3-containing propargylic alcohol derivatives via the corresponding allenes

✍ Scribed by Takashi Yamazaki; Yohsuke Watanabe; Nao Yoshida; Tomoko Kawasaki-Takasuka


Book ID
116909554
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
773 KB
Volume
68
Category
Article
ISSN
0040-4020

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✍ Alberto Haces; EugΓ©ne M.G.A. van Kruchten; William H. Okamura πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 257 KB

summaq: The reactions of (CH3)2CuLl with various C-8 epuneric propargyllc esters derived from Grundmann's ketone, a C/D steroad fragment orlglnating from vltanun D3, lead to the corresponctrng allenes, the stereochermstry of which ln&cate a preferred ant1 1,3-substltutlon. A very recent communicati