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Facile Construction of the Benzofuran and Chromene Ring Systems via PdII-Catalyzed Oxidative Cyclization.

✍ Scribed by So Won Youn; Jeong Im Eom

Publisher: John Wiley and Sons
Year: 2005
Weight: 36 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200548125

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✦ Synopsis

Abstract

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Diastereoselective Construction of cis 2

Diastereoselective Construction of cis 2,6-Disubstituted Tetrahydropyran Rings via In(OTf)3-Catalyzed Intramolecular 2,5-Oxonium-ene Cyclization: Synthetic Studies Towards the Total Synthesis of Zampanolide and Dactylolide.

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Diastereoselective construction of cis 2

Diastereoselective construction of cis 2,6-disubstituted tetrahydropyran rings via In(OTf)3-catalyzed intramolecular 2,5-oxonium-ene cyclization: synthetic studies towards the total synthesis of zampanolide and dactylolide

✍ Teck-Peng Loh; Jian-Ying Yang; Li-Chun Feng; Yan Zhou 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 129 KB

Diastereoselective construction of 2,6-disubstituted tetrahydropyrans with an exocyclic double bond was achieved via the In(OTf) 3 -catalyzed intramolecular 2,5-oxonium-ene cyclization. Its application was further demonstrated by the synthesis of a common intermediate for both zampanolide and dactyl