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Facile aryl-aryl exchange between the palladium center and phosphine ligands in palladium(II) complexes

✍ Scribed by Kong, Kwang Cheng; Cheng, Chien Hong


Book ID
121868378
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
430 KB
Volume
113
Category
Article
ISSN
0002-7863

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✍ Adrien T. Normand; Mikhail S. Nechaev; Kingsley J. Cavell 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 505 KB

## Abstract A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η^3^‐C~3~H~5~)(tmiy)(PR~3~)]BF~4~ (tmiy=tetramethylimidazolin‐2‐ylidene, PR~3~=phosphane), precursors to monoligated Pd^0^ species, with aryl electrophiles yielding 2‐arylimidazolium salt is reported. Experiments e