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Facile and Selective O -Alkyl Transesterification of Primary Carbamates with Titanium(IV) Alkoxides †

✍ Scribed by Shapiro, Gideon; Marzi, Martin

Book ID
120997475
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
67 KB
Volume
62
Category
Article
ISSN
0022-3263

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Facile Formation of Hexacyclic [Al3O2Cl] Aluminum and Alkoxide-Bridged Titanium Complexes: Reactions of AlMe3 with [Ti(L)Cl2] [L = 2,2′-Methylenebis(6-tert-butyl-4-methylphenolato)]
✍ Dao Zhang 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

## Abstract The titanium dichloride complex [(L)TiCl~2~] [L = 2,2′‐methylenebis(6‐__tert‐__butyl‐4‐methylphenolato)] (1) reacted with trimethylaluminum (AlMe~3~) in a 1:2 ratio to give a trimetallic aluminum complex of the composition [(L)(AlMe~2~)~3~(μ‐Cl)] (2) with a symmetric six‐membered ring [