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Facile Access to Optically Active Ferrocenyl Derivatives with Direct Substitution of the Hydroxy Group Catalyzed by Indium Tribromide.

✍ Scribed by Paola Vicennati; Pier Giorgio Cozzi

Publisher: John Wiley and Sons
Year: 2007
Weight: 51 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200735175

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✦ Synopsis

Abstract

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## Abstract Treatment of {[(benzyloxy)carbonyl]amino}‐substituted sulfones **1** with 2‐[(trimethylsilyl)oxy]furan (**2**) in the presence of InCl~3~ as a catalyst at room temperature produced the __γ__‐butenolactone derivatives **3** and **4** containing a protected amino group (__Scheme 1__). The