Facile Access to Key Reactive Intermediates in the Pd/PR3-Catalyzed Telomerization of 1,3-Butadiene
✍ Scribed by Peter J. C. Hausoul; Dr. Andrei N. Parvulescu; Dr. Martin Lutz; Prof. Dr. Anthony L. Spek; Dr. Pieter C. A. Bruijnincx; Prof. Dr. Bert M. Weckhuysen; Prof. Dr. Robertus J. M. Klein Gebbink
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 400 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract Cycloadditions of various 1,3‐dipoles to methyl (__S__)‐1‐__tert__‐butoxycarbonyl‐3‐[(__E__)‐cyanomethylidene]‐2‐pyrrolidinone‐5‐carboxylate (**9**) were studied. Reactions of **9** with diazomethane (**10**) and 2,4,6‐trimethoxy‐benzonitrile oxide (**11**), carried out under neutral co