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Fabrication of Chemically Tethered Binary Polymer-Brush Pattern through Two-Step Surface-Initiated Atomic-Transfer Radical Polymerization

✍ Scribed by Feng Zhou; Lei Jiang; Weimin Liu; Qunji Xue


Book ID
102496265
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
196 KB
Volume
25
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Summary: The communication provides a novel and alternative route to generate chemically tethered binary polymer‐brush pattern through two‐step surface‐initiated atomic‐transfer radical polymerization (SI‐ATRP). Polymer brush‐1 was prepared by SI‐ATRP, passivated by a reaction with NaN~3~, and etched with UV irradiation through a transmission electron microscopy grid to create exposed sites for the subsequently attached initiator on which polymer brush‐2 was grown.

Schematic representation of the resultant binary polymer brush patterns.

imageSchematic representation of the resultant binary polymer brush patterns.


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