Fabrication of Chemically Tethered Binary Polymer-Brush Pattern through Two-Step Surface-Initiated Atomic-Transfer Radical Polymerization
✍ Scribed by Feng Zhou; Lei Jiang; Weimin Liu; Qunji Xue
- Book ID
- 102496265
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 196 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1022-1336
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Summary: The communication provides a novel and alternative route to generate chemically tethered binary polymer‐brush pattern through two‐step surface‐initiated atomic‐transfer radical polymerization (SI‐ATRP). Polymer brush‐1 was prepared by SI‐ATRP, passivated by a reaction with NaN~3~, and etched with UV irradiation through a transmission electron microscopy grid to create exposed sites for the subsequently attached initiator on which polymer brush‐2 was grown.
Schematic representation of the resultant binary polymer brush patterns.
imageSchematic representation of the resultant binary polymer brush patterns.
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