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Fabrication of Amino-Terminated Multiwalled Carbon Nanotubes via Layer-by-Layer Self-Assembly Approach

✍ Scribed by Peng Zhang; Xiaobin Huang; Jianwei Fu; Yawen Huang; Xiaozhen Tang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
544 KB
Volume
295
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

MWCNT‐based composites have been successfully synthesized via layer‐by‐layer self‐assembly of crosslinked polyphosphazene nanoparticles on the surface of MWCNTs. The amino‐terminated CNTs were characterized by XPS, FT‐IR spectroscopy, EDS, XRD and TEM. The degree of functionalization could be controlled by simply changing the mass of hexachlorocyclotriphosphazene with 4,4′‐diaminodiphenyl ether. The activity of the surface amino groups was confirmed by the reaction of these groups with HAuCl~4~. In addition, the effects of the mass of HCCP and ODA ratios on the content of the surface amino groups was also investigated.

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