A polylactide (PLA type LA 0200 K) was spun in high-speed melt spinning and spin drawing processes. The fibers were characterized with regard to the degree of crystallinity, the orientation, and the textile physical properties. The polymer was produced by a reactive extrusion polymerization process,
Fabrication of Aligned Poly(L-lactide) Fibers by Electrospinning and Drawing
β Scribed by Amalina M. Afifi; Hajime Nakajima; Hideki Yamane; Yoshiharu Kimura; Shigeyuki Nakano
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 893 KB
- Volume
- 294
- Category
- Article
- ISSN
- 1438-7492
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β¦ Synopsis
Abstract
A new target collector was designed for taking up aligned nanofibers by electrospinning. The collector consists of a rotor around which several fins were attached for winding electrospun filaments continuously in large amounts. The alignment of the nanofibers wound on the collector was affected by the electrospinning conditions, such as the needleβtoβcollector distance and the applied voltage, but not by the rotation speed of the collector. At a voltage of 0.5βkVβΒ·βcm^β1^, about 60% of the fibers were found to be aligned within an angle ofβΒ±β5Β° relative to the rotational direction of the collector. The fiber alignment was improved to 90% by drawing the fiber bundle 2β3 times at 110βΒ°C. The drawing was also effective for crystal orientation of the fibers as revealed by WAXD. The drawn fibers show improved mechanical properties.
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π SIMILAR VOLUMES
## Abstract Fibrous poly(Lβlactide) (PLLA) and bicomponent PLLA/poly(ethylene glycol) mats were prepared by electrospinning and then were coated with chitosan. The presence of chitosan coating was proved by scanning electron microscopy and by fluorescence microscopy. On contact with blood, the chit