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Fabrication and Characterization of Ionic Conducting Nanofibers

✍ Scribed by Alexis Laforgue; Lucie Robitaille; Asmae Mokrini; Abdellah Ajji


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
498 KB
Volume
292
Category
Article
ISSN
1438-7492

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✦ Synopsis


Abstract

The electrospinning method was used to fabricate nanostructures of Nafion‐poly(vinyl alcohol) (PVA) and Nafion‐poly(ethylene oxide) (PEO). Depending on the ratio between the two polymers, nanospheres and/or nanofibers could be obtained in a reproducible manner. The Nafion‐PVA mats were found to be more conductive than the Nafion‐PEO ones, possibly because of their better mechanical properties when swollen by water. The fiber morphology was always found to be more conductive than the sphere morphology. However, all electrospun mats presented ionic conductivities slightly lower than extruded Nafion 115 or Nafion‐PVA cast films.

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✍ Sujith Nair; Sudarshan Natarajan; Seong H. Kim 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB

## Abstract **Summary:** Electrically conducting polypyrrole‐poly(ethylene oxide) (PPy‐PEO) composite nanofibers are fabricated via a two‐step process. First, FeCl~3~‐containing PEO nanofibers are produced by electrospinning. Second, the PEO‐FeCl~3~ electrospun fibers are exposed to pyrrole vapor f